In this communication, NASICON-type glass-ceramic (lithium germanium phosphate, LiGe2(PO4)3) was prepared as lithium super ionic conductor using aluminum as dopant for ionic conduction improvement. The solid solution was Li1 + xAlxGe2-x(PO4)3 (x = 0.5) that Ge4+ ions were partially substituted by Al3+ ions in crystal structure. Initial glasses were converted to glass-ceramics at different times and temperatures for maximum ionic conduction achievement. The crystals were characterized by X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM), Energy-Dispersive X-ray spectroscopy (EDX), Differential Scanning Calorimetry (DSC) and Complex Impedance Spectroscopy (CIS) methods. The maximum lithium ion conductivity for glass-ceramic, 5.32 × 10−3 S/cm at 26 °C was obtained for specimen crystallized at 850 °C for 8 h with minimum activation energy of 0.286 eV. Increasing the crystallization temperature results in secondary phase formation in grain boundary and increasing in crystallization time results in microcracks formation in specimen. Both phenomena decreased the ionic conductivity.
