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Mozhgan Pirhayati

Mozhgan Pirhayati

Academic rank: Assistant Professor
ORCID:
Education: PhD.
ScopusId:
HIndex:
Faculty: science
Address:
Phone: 32456518-365

Research

Title
تثبیت نانوذرات پالادیوم بر روی نانوذرات مغناطیسی عاملدار شده با مایع یونی-تری اتیل آمونیم کلرید:به عنوان یک کاتالیست قابل جداسازی مغناطیسی، پایدار و قابل بازیافت در واکنش های متقاطع Suzuki-Miyaura
Type
JournalPaper
Keywords
Magnetic Nanoparticles Palladium Heterogeneous nanocatalyst Suzuki
Year
2017
Journal TETRAHEDRON LETTERS
DOI
Researchers Mozhgan Pirhayati

Abstract

A facile procedure was applied to successfully synthesize novel Pd nanoparticles immobilized on triethanolamine- functionalized magnetic nanoparticles [Fe3O4/IL/Pd]. Diverse characterizations (HR-TEM, XRD, FT-IR, TGA, EDX, FE-SEM, ICP, XPS and VSM) were carried out to identify intrinsic traits of the nanoparticles. At room temperature, Fe3O4/IL/Pd demonstrated high catalytic activity toward Suzuki-Miyaura cross-coupling reactions in aqueous solution. Based on the results, Fe3O4/IL/Pd acted as zwitterionic IL-type heterogeneous catalyst, which could be separated from the reaction mixture, conveniently. Moreover, it exhibited excellent recyclability for at least eight cycles without considerable loss of its activity.