In this study, stream sediment geochemical data have been subjected to robust principal components analysis (RPCA) and singularity mapping (SM) to enhance and map significant multivariate geochemical anomalies (i.e., mineralization-related) in Ahar area, NW Iran. The RPCA was applied to (a) account for the compositional nature of stream sediment geochemical data using suitable log-ratio transformation, (b) modulate the effect of outliers in component estimation and (c) derive a multivariate geochemical footprint of mineralization. The SM was applied to extract anomalous patterns of the multivariate geochemical footprint of mineralization. The exploration targets were then delineated using Students t-statistics analysis. The correlations of mapped exploration targets with the known mineral occurrences and mineralization-related patterns were further evaluated using normalized density index and overall accuracy analyses.