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Mohammad Almasi

Mohammad Almasi

Academic rank: Associate Professor
ORCID:
Education: PhD.
ScopusId:
HIndex:
Faculty: science
Address: Malayer University, Faculty of Science, Department of Applied Chemistry
Phone: 08132355492

Research

Title
Study of Nonideality Behavior of p‑Methylacetophenone and 1‑Alkanol Mixtures from Measurement and Modeling of Density and Viscosity
Type
JournalPaper
Keywords
density, viscosity, 1-alaknol, molecular interactions
Year
2023
Journal JOURNAL OF CHEMICAL AND ENGINEERING DATA
DOI
Researchers Mohammad Almasi

Abstract

The aim of this work is to investigate experimentally and theoretically thermophysical properties (density and viscosity) and derived properties (excess molar volume and viscosity deviation) of pmethylacetophenone + alkanols (C5 to C9) in the range of 293.15 to 323.15 K and a pressure of 0.1 MPa. The properties studied were density, viscosity, excess molar volume, and deviation in viscosity. To model the density of the liquid mixtures, we used the perturbed chain-statistical associating fluid theory equation of state (PC-SAFT EoS) and the volume translated Peng-Robinson-Stryjek-Vera equation of state (VTPRSV EoS). Using a correlation approach an overall deviation of 0.34% and 0.28% was obtained, respectively, while good predictive results were obtained (0.44% using PC-SAFT EoS and 0.46% using VTPRSV EoS). Also, we use two correlations without fitted parameters (Kendall-Munroe correlation and Nguyenhuynh correlation) to model the experimental viscosity and obtained an overall deviation of 5.07% and 3.07%. In addition, the Redlich−Kister correlation (with three fitted parameters) was able to correctly correlate the excess molar volume and the deviation in viscosity for all mixtures. Finally, the results obtained from the work have been disc