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Mohammad Almasi

Mohammad Almasi

Academic rank: Associate Professor
ORCID:
Education: PhD.
ScopusId:
HIndex:
Faculty: science
Address: Malayer University, Faculty of Science, Department of Applied Chemistry
Phone: 08132355492

Research

Title
Correlation Studies of Cyclohexanone/(C5−C10) Alkan-1-ol Binary Mixtures: PC-SAFT Model and Free Volume Theory
Type
JournalPaper
Keywords
pc- saft, free volume
Year
2018
Journal JOURNAL OF CHEMICAL AND ENGINEERING DATA
DOI
Researchers Mohammad Almasi

Abstract

In this article the behavior of cyclohexanone + 1-alkanol, namely, 1-pentanol, 1-hexanol, 1-heptanol, 1-octanol, 1-nonanol, and 1- decanol, binary mixtures through the density and viscosity measurements has been studied as a function of composition and within the temperature range of 293.15−323.15 K. The excess molar volume and viscosity deviations have been calculated and fitted by the Redlich− Kister polynomial equation. For binary mixtures of cyclohexanone + 1- pentanol, values of excess molar volume are negative and for other mixtures are positive. For all binary systems viscosity deviations are negative and increase with the alkyl chain of alcohol. The results provide information on the interactions among the molecules in the pure state as well as the binary liquid mixtures. The measured densities and viscosities have been applied to test the applicability of the PCSAFT and free volume models.